Bis(1,10-phenanthroline-5,6-dione-κ2 N,N′)silver(I) 2-hydroxy-3,5-dinitrobenzoate
نویسندگان
چکیده
In the cation of the title salt, [Ag(C(12)H(6)N(2)O(2))(2)](C(7)H(3)N(2)O(7)), the Ag(I) atom is coordinated in a distorted tetra-hedral geometry by four N atoms from two 1,10-phenanthroline-5,6-dione ligands, while the 3,5-dinitro-salicylate anion has only a short contact [2.847 (6) Å] between one of its O atoms and the Ag(I) atom. The dihedral angle between the two 1,10-phenanthroline-5,6-dione ligands is 58.4 (1)°. There is an intra-molecular O-H⋯O hydrogen bond in the 3,5-dinitro-salicylate anion.
منابع مشابه
Diiodido(1,10-phenanthroline-5,6-dione-κ2 N,N′)mercury(II)
The Hg(II) atom in the title complex, [HgI(2)(C(12)H(6)N(2)O(2))], is tetra-hedrally coordinated by the N atoms of the chelating 1,10-phenanthroline-5,6-dione ligand and two I atoms. The range of tetra-hedral angles is broad, viz. 68.94 (17)° for the chelate angle to a wide 132.627 (15)° for the I-Hg-I angle. The ligand mol-ecule is non-planar with the O atoms lying 0.422 (5) and -0.325 (5) Å o...
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